Bonding and Electron Delocalization in Ruthenium(III) σ-Arylacetylide Radicals [trans-Cl(η2-dppe)2RuC≡C(4-C6H4X)]+ (X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2): Misleading Aspects of the ESR Anisotropy
Organometallics2009Vol. 28(7), pp. 2253–2266
Citations Over TimeTop 10% of 2009 papers
N. Gauthier, Noureddine Tchouar, Frédéric Justaud, Gilles Argouarch, Marie P. Cifuentes, Loïc Toupet, Daniel Touchard, Jean‐François Halet, Stéphane Rigaut, Mark G. Humphrey, Karine Costuas, Frédéric Paul
Abstract
The bonding within the series of [trans-Cl(η2-dppe) 2RuC≡C(4-C6H4X)]n+ complexes (1-Xn+; n = 1, 0 and X = NO2, C(O)H, C(O)Me, F, H, OMe, NMe2) has been examined by IR, ESR, and UV-vis-near-IR spectroscopy together with computational modeling. A strong
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