Electronic Effects of the Anionic Ligand in Ruthenium-Catalyzed Olefin Metathesis
Organometallics2009Vol. 28(4), pp. 944–946
Citations Over TimeTop 13% of 2009 papers
Abstract
Synthesis of a family of Ru−catecholate catalysts, in which catechol acidity spans 4.5 pKa units, enables evaluation of electronic effects in Ru-catalyzed olefin metathesis. The metathesis activity drops as the anionic ligands become more electron-deficient, in contrast to the trend established for the Schrock group 6 catalysts.
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