Efficient and Reversible Fixation of Carbon Dioxide by NCN-Chelated Organoantimony(III) Oxide
Organometallics2009Vol. 28(8), pp. 2633–2636
Citations Over TimeTop 10% of 2009 papers
Abstract
The dimeric organoantimony(III) oxide (ArSbO)2 (Ar = NCN chelating ligand, C6H3-2,6-(CH2NMe2)2) was obtained by the reaction of the parent ArSbCl2 compound with KOH. This oxide is able to bind carbon dioxide with formation of the monomeric, air-stable carbonate ArSbCO3. In turn, carbon dioxide can be easily eliminated from this carbonate by prolonged heating to 130 °C to recover (ArSbO)2.
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