Novel Ruthenium- or Iron-Containing Tetraynes as Precursors of Mixed-Metal Oligomers
Organometallics1996Vol. 15(6), pp. 1530–1531
Citations Over TimeTop 1% of 1996 papers
Abstract
The preparation of the novel carbon-rich iron- and ruthenium-containing tetraynes 3 and 5 from HC⋮CC6H4C⋮CSiiPr3 (2), via catalyzed CC coupling and ruthenium−vinylidene activation, is described. Their desilylated products 4 and 6, which possess two π-conjugated “rod”-shaped arms and C⋮CH hands, have been used as monomers for access to novel mixed d6/d8 metal containing rigid and flexible units (7 and 8) or unidimensional (9) oligomers.
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