A New Reagent for Chiral Recognition Containing a Five-Membered Palladacycle with a σ(Pd-Csp2,ferrocene) Bond
Organometallics1997Vol. 16(15), pp. 3261–3266
Citations Over TimeTop 10% of 1997 papers
Abstract
The chiral recognition of β-hydroxyphosphines and the discrimination of (±)-bis(diphenylphosphino)-1,1'-binaphthyl can be easily achieved using the bis(cyclopalladated) complex (RP,SC,SC,RP)-(+)-[Pd{[(η5-C5H3)CH(CH3)N(CH3)2]Fe(η5-C5H5)}(μ-Cl)]2 (1).
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