Reactions of a Chelated Cyclopentadienylcobalt(I) Complex with 3,3-Disubstituted Cyclopropenes: Formation of Isoprene, Vinylcarbene, and 1-Phosphadiene Ligands at the Metal

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Abstract

(Di-tert-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.

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