Magnesiation of Isodicyclopentadiene. Formation of Sandwich and Monomeric Complexes and the Stereoselectivity of Their Reactions with Transition Metal Halides
Organometallics1999Vol. 18(13), pp. 2531–2535
Citations Over Time
Olivier Gobley, Sébastien Gentil, Jeffrey D. Schloss, Robin D. Rogers, Judith C. Gallucci, Philippe Meunier, B. Gautheron, Leo A. Paquette
Abstract
The exo,exo-bis(isodicyclopentadienyl)magnesium sandwich and the monomeric exo-(isodicyclopentadienyl)butylmagnesium TMEDA complex have been synthesized and characterized by 1H and 13C NMR spectroscopy in C6D6 solution. The solid-state structures were determined by X-ray crystallography. The stereoselectivity with which both moisture-sensitive compounds react with TiCl3·3THF and ZrCl4 was assessed and suitably compared to related observations recorded for alkali metal (Li+, Na+, and K+) complexes of isodicyclopentadiene.
Related Papers
- → Shell-model calculation of defect energies in alkali halides employing crystal-independent interionic potential parameters(1978)11 cited
- → High-pressure phase transitions in some alkali halides(1990)7 cited
- → Formation of Additive V Centers in Disks Prepared from Powdered Alkali Halides(1962)2 cited
- → Can molecular alkali halides be photodesorbed from metallic and nonpolar dielectric surfaces?(1981)
- → Systematic Evaluation of Parameterization Approaches for the ePPC-SAFT Model for Aqueous Alkali Halide Solutions. II. Alkali Bromides, Iodides, Fluorides, And Lithium Halides(2023)