Unsymmetrically Substituted Iridium(III)−Carbene Complexes by a CH-Activation Process
Organometallics2000Vol. 19(9), pp. 1692–1694
Citations Over TimeTop 10% of 2000 papers
Abstract
The synthesis of the metalhydride Cp*(L‘)IrH+OTf - (L‘ = 1-(2-cyclohexenyl)-3-cyclohexylimidazolin-2-ylidene, OTf = OSO2CF3) is achieved by a cyclohexane to cyclohexene transformation at the N-heterocyclic carbene ligand based on a CH-activation/β-hydrogen migration process at the Ir(III) center under mild conditions. The synthetic route to Cp*(L‘)IrH+OTf - and NMR spectroscopic and X-ray structural data are presented.
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