Selecting core-hole localization or delocalization in CS2 by photofragmentation dynamics

Citations Over TimeTop 10% of 2015 papers

Abstract

Electronic core levels in molecules are highly localized around one atomic site. However, in single-photon ionization of symmetric molecules, the question of core-hole localization versus delocalization over two equivalent atoms has long been debated as the answer lies at the heart of quantum mechanics. Here, using a joint experimental and theoretical study of core-ionized carbon disulfide (CS2), we demonstrate that it is possible to experimentally select distinct molecular-fragmentation pathways in which the core hole can be considered as either localized on one sulfur atom or delocalized between two indistinguishable sulfur atoms. This feat is accomplished by measuring photoelectron angular distributions within the frame of the molecule, directly probing entanglement or disentanglement of quantum pathways as a function of how the molecule dissociates. Molecular core levels are localized around a single atomic site, but for indistinguishable atoms, photoionised core-holes can either be seen as localized or delocalized. Using a prototypical symmetric system, CS2, Guillemin et al. show that these states can be disentangled by fragmentation dynamics.

Related Papers

• IDENTIFIKASI MODE RUSAK JAMAK (MULTI-FAULTS) BANTALAN MENGGUNAKAN ANALISIS ENVELOPE PADA TURBIN ANGIN Horizontal Axis(2018)
• EVALUASI PERLAKUAN AKUNTANSI HARGA POKOK PRODUK RUSAK PADA PT. MULIAPRIMA REPLICATAMA SEMARANG(2000)
• ANALISIS PERLAKUAN AKUNTANSI PRODUK RUSAK PADA PT. AJINOMOTO INDONESIA MOJOKERTO FACTORY(2017)
• Perbedaan Kinerja Karyawan Sebelum dan Sesudah Penerapan Uraian Pekerjaan(2001)