A laser flash photolysis study of p-tolyl(trifluoromethyl)carbene
Journal of the Chemical Society Perkin Transactions 21998Iss. 5, pp. 1093–1100
Citations Over TimeTop 20% of 1998 papers
Atnaf Admasu, Anna D. Guđmundsdóttir, Matthew S. Platz, David S. Watt, Stephan Kwiatkowski, Peter J. Crocker
Abstract
3-p-Tolyl-3-trifluoromethyldiazirine was studied by laser flash photolysis (LFP) to obtain the absolute kinetics of p-tolyl(trifluoromethyl)carbene 1. The absolute rate constants for the reactions of 1 with pyridine, ketones and quenchers of biological interest were obtained. The implications of the data for photoaffinity labeling experiments are discussed.
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