Supercritical fluid processing: a new route for materials synthesis
Journal of Materials Chemistry1999Vol. 9(1), pp. 67–75
Citations Over TimeTop 10% of 1999 papers
François Cansell, Bernard Chevalier, Alain Demourgues, J. Étourneau, Christophe Even, Vincent Pessey, S. Petit, A. Tressaud, François Weill
Abstract
Supercritical fluids exhibit a range of unusual properties that can be exploited for new reactions which are qualitatively different from those involving classical solid state chemistry. After giving a brief introduction to these fluids we describe their use in inorganic chemistry and related fields. We then present two examples concerning different areas of solid state chemistry: (i) the formation of novel inorganic nanoparticles; (ii) the preparation of new open-structure oxy(hydroxy)fluorides, thus showing the advantages of this supercritical fluid processing that can be seen as an alternative method to regular solution chemistry or solid-gas reactions.
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