Self-assembly of zinc aminoporphyrins

Citations Over TimeTop 10% of 1999 papers

Abstract

The aniline–zinc porphyrin interaction is an order of magnitude weaker than the corresponding pyridine–zinc porphyrin interaction, but it is still strong enough to cause self-assembly of zinc aminoporphyrins in solution. Three isomeric systems are reported, two form self-assembled dimers, but the geometry of the third forces it to form an open chain oligomer. The stabilities and structures of the complexes have been determined using 1H NMR spectroscopy.

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