A novel pentamanganese(II) cluster produced by a controlled self assembly process; an exact match between the coordination algorithm of the metals and the ligand binding site arrangement
Chemical Communications1999Iss. 4, pp. 347–348
Citations Over TimeTop 12% of 1999 papers
Craig J. Matthews, Zhiqiang Xu, Sanat K. Mandal, Laurence K. Thompson, Kumar Biradha, K. Poirier, Michael J. Zaworotko
Abstract
The tetradentate ligand phaap combines a bridging alkoxide oxygen and diazine and pyridine nitrogen donors, with five critically positioned binding sites, and on reaction with Mn(ClO4)2·6H2O undergoes a controlled self assembly to produce a unique trigonal bipyramidal oxygen bridged metal cluster with an exact match between the coordination requirements of the five six-coordinate metals and the donor arrangements of the six coordinated ligands.
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