Singlet–triplet bistability in a 1,3-phenylene-based bis(aminoxyl) diradical
Chemical Communications1999Iss. 13, pp. 1249–1250
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Abstract
Rapid quenching of the title bis(aminoxyl) 1 in 2-methyltetrahydrofuran from ambient temperature to cryogenic temperatures (5 K or below) produces 1 in its singlet state, which slowly converts at low temperatures, with an S-shaped time-dependence, to the triplet ground state.
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