The origin of the second relaxation process in the [Mn12O12(O2CR)16(H2O)4] single-molecule magnets: ‘Jahn–Teller isomerism’ in the [Mn12O12] core
Chemical Communications1999Iss. 19, pp. 1973–1974
Citations Over TimeTop 10% of 1999 papers
Ziming Sun, Daniel Ruiz, David N. Hendrickson, N. R. Dilley, M. B. Maple, Mónica Soler, Kirsten Folting, George Christou, Joan Ribas
Abstract
The origin of the second, faster relaxation process in Mn12 molecules has been identified as a different relative orientation of the Jahn–Teller elongation axes of the MnIII ions, which we have termed ‘Jahn–Teller isomerism’.
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