Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions
Journal of the Chemical Society Dalton Transactions2001Iss. 6, pp. 772–773
Citations Over TimeTop 15% of 2001 papers
Abstract
Two novel hexadecametal–oxygen cluster compounds, {Ni[(NH2)2(C2H4)2NH]2}3[PMoVI5MoV3VIV8O44]·[(NH2)2(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4)2NH]2}2Na[PMoVI6MoV2VIV8O44]·8H2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal–oxygen host shell is observed in 2.
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