The regioselective aminohydroxylation of allylic carbamates
Chemical Communications2001Iss. 20, pp. 2078–2079
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Abstract
The synthesis and aminohydroxylation of a series of acyclic allylic carbamates is described: the formation of a putative O=Os=NR linkage between the transition metal and substrate is proposed to account for the high levels of regioselectivity that were observed; proof of the structure of one of the aminohydroxylation products was obtained through X-ray crystallography.
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