Aromatic C–F activation at Ni in the presence of a carbon–chlorine bond: the nickel mediated synthesis of new pyrimidines
Journal of the Chemical Society Dalton Transactions2002Iss. 3, pp. 297–297
Citations Over TimeTop 10% of 2002 papers
Abstract
Treatment of [Ni(COD)2]/PCy3 with 5-chloro-2,4,6-trifluoropyrimidine affords the C–F activation product trans-[NiF(4-C4N2ClF2)(PCy3)2] 2, which reacts with iodine to form 5-chloro-2,6-difluoro-4-iodo-pyrimidine 5.
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