Reaction of singlet oxygen with Ir(i) and Rh(i) thiolato complexes: oxidative addition vs. S-oxidationElectronic supplementary information (ESI) available: experimental crystallographic details. See http://www.rsc.org/suppdata/cc/b1/b110396m/
Chemical Communications2002Iss. 6, pp. 570–571
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David Ho, Rehana Ismail, Nestor Franco, Ruomei Gao, Edward P. Leverich, I. Tsyba, N.N. Ho, Robert Bau, Matthias Selke
Abstract
Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.
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