Evidence for through-framework electron transfer in intrazeolite photochemistry. Case of Ru(bpy)32+ and methylviologen in novel delaminated ITQ-2 zeolite

Citations Over TimeTop 22% of 2002 papers

Abstract

A sample of novel delaminated zeolite ITQ-2 containing Ru(bpy)3(2+) on the external cups and MV2+ included in the independent and not connected channels has been prepared; emission and time-resolved laser flash photolysis has shown unambigously that photoinduced electron transfer from Ru(bpy)3(2+) to MV2+ occurs through the zeolite framework.

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