Phase behaviour of room temperature ionic liquid solutions: an unusually large co-solvent effect in (water + ethanol)
Physical Chemistry Chemical Physics2002Vol. 4(10), pp. 1701–1703
Citations Over TimeTop 10% of 2002 papers
Vesna Najdanovic–Visak, José M. S. S. Esperança, Luís Paulo N. Rebelo, Manuel Nunes da Ponte, Henrique J. R. Guedes, Kenneth R. Seddon, Jerzy Szydłowski
Abstract
A surprising mixed solvent effect, both in its magnitude and direction, has been found in the phase diagram of the ternary mixture of ([C4mim][PF6] + (water + ethanol)). For a molar ratio of 1∶1 of water to ethanol, the co-solvent effect in the near-critical demixing temperature can be as large as 80 K.
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