From rational octahedron design to reticulation serendipity. A thermally stable rare earth polymeric disulfonate family with CdI2-like structure, bifunctional catalysis and optical properties
Chemical Communications2002Iss. 13, pp. 1366–1367
Citations Over TimeTop 21% of 2002 papers
Natalia Snejko, C. Cascales, Berta Gómez‐Lor, Enrique Gutiérrez‐Puebla, Marta Iglesias, C. Ruı́z-Valero, Ángeles Monge
Abstract
A new family of lanthanide disulfonates Ln(OH)(NDS)(H2O), (Ln = La, Pr and Nd; NDS=1,5-naphthalenedisulfonate) was designed and hydrothermally synthesized; this is the first example of a disulfonate ligand coordinated to six different Ln atoms; these materials, with high thermal stability, act as active and selective bifunctional catalysts in oxidation and epoxide ring opening; strong luminescence from the optically active Nd center was observed. © 2002 Royal Society of Chemistry.
Related Papers
- → Color Tuning and White Light Emission via in Situ Doping of Luminescent Lanthanide Metal–Organic Frameworks(2013)219 cited
- → Electronegativity and structural characteristics of lanthanides(2004)41 cited
- New Opportunities for Lanthanide Luminescence(2007)
- → Complexation of lanthanide nitrates(1992)6 cited
- → Extraction of macro- and microamounts of lanthanides by D2EHPA(1990)6 cited