First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [{Cu(1,2-pn)2}7{V16O38(H2O)}2]·4H2O
Chemical Communications2002Iss. 18, pp. 2126–2127
Citations Over TimeTop 10% of 2002 papers
Abstract
The hydrothermal reaction of V2O5, Cu(CH3COO)2.H2O, 1,2-diaminopropane and [N(CH3)4]OH yields the novel three-dimensional open-framework solid [(Cu(1,2-pn)2)7-(V16O38(H2O))2].4H2O constructed from the new mixed-valence [V16O38(H2O)]7- clusters interconnected through mu 2-[Cu(1,2-pn)2]2+ groups.
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