A rapid and effective synthesis of propylene carbonate using a supercritical CO2–ionic liquid system
Chemical Communications2003Iss. 7, pp. 896–897
Citations Over TimeTop 1% of 2003 papers
Abstract
The synthesis of propylene carbonate from propylene oxide and carbon dioxide under supercritical conditions in the presence of 1-octyl-3-methylimidazolium tetrafluoroborate was achieved in nearly 100% yield and 100% selectivity within 5 minutes, whose TOF value is 77 times larger than those so far reported.
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