A novel non-template solution approach to fabricate ZnO hollow spheres with a coordination polymer as a reactantElectronic supplementary information (ESI) available: X-ray photoelectron spectra and energy-dispersive X-ray analysis of the products. See http://www.rsc.org/suppdata/nj/b3/b304787c/
New Journal of Chemistry2003Vol. 27(10), pp. 1518–1518
Citations Over TimeTop 10% of 2003 papers
Abstract
The methods of coordination chemistry are extended to fabricate hollow spheres of inorganic materials. In particular, in the present work a novel approach is successfully put forward to synthesize ZnO submicrometer hollow spheres, in which the coordination polymer [Zn(4,4′-bipy)(NCS)2]n with a 1D chain structure is introduced as a reactant. In this approach, no additional template materials are needed to obtain submicrometer hollow-sphere structures in the reaction process. A possible mechanism is also proposed.
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