Azines possessing strong push–pull donors/acceptors
Chemical Communications2004Iss. 16, pp. 1842–1843
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D.D. Choytun, L.D. Langlois, Thomas Johansson, Charles L. B. Macdonald, Gary W. Leach, Noham Weinberg, Jason A. C. Clyburne
Abstract
Azines (R(2)C[double bond, length as m-dash]N-N[double bond, length as m-dash]CR(2)) are 2,3-diaza analogues of 1,3-butadiene. In this report we show that strong polarisation of the azine imparts structural features consistent with delocalization within the azine fragment; NLO properties for the azines are also reported.
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