New perspectives in hydroformylation : a para-hydrogen study
Chemical Communications2004Iss. 16, pp. 1826–1827
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Abstract
NMR studies on the reaction of Ir(CO)(PPh(3))(2)(eta(3)-C(3)H(5)) with para-H(2) and CO enable the complete mapping of the hydroformylation mechanism for an iridium monohydride catalyst via the detection of species which include iridium acyl and alkyl dihydride intermediates.
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