A very large Rh–Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ion by time-resolved synchrotron X-ray diffraction
Chemical Communications2004Iss. 19, pp. 2144–2145
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Philip Coppens, Oksana Gerlits, I.I. Vorontsov, Andrey Kovalevsky, Yu‐Sheng Chen, Tim Graber, Milan Gembický, Irina Novozhilova
Abstract
A very large Rh-Rh contraction of approximately 0.85 A occurs on excitation of the [Rh(2)(1,8-diisocyano-p-menthane)(4)](2+) ion to its triplet state.