Terminal co-ligand directed synthesis of a neutral, non-interpenetrated (10,3)-a metal–organic framework
Chemical Communications2005Iss. 16, pp. 2095–2097
Citations Over TimeTop 10% of 2005 papers
Abstract
A neutral, non-interpenetrated porous metal-organic framework (MOF) having (10,3)-a topology, Cu(3,5-PDC)(DMF)(py), (DMF =N,N'-dimethylformamide, py = pyridine), has been constructed via the assembly of the achiral tri-connected building blocks 3,5-pyridinedicarboxylate (3,5-PDC) and CuN(CO2)2, synthesized in situ. Similarly, a 2D structure having (6,3) topology has been generated, each by means of terminal co-ligand directed synthesis.
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