A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of η3, η5, η6and bridging modes of bonding to Li+, Na+, K+, Tl+and Ca2+ions
Chemical Communications2006Iss. 17, pp. 1872–1874
Citations Over TimeTop 10% of 2006 papers
Abstract
A tris-pyrazolylborate ligand bearing ether appendages is shown to be a potential hemilabile ligand based on NMR studies and structural characterization of its eta3, eta5, eta6, and micro-binding modes in coordination with Li+, Na+, K+, Tl+, and Ca2+ ions.
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