Self-assembly of luminescent ternary complexes between seven-coordinate lanthanide(iii) complexes and chromophore bearing carboxylates and phosphonates
Dalton Transactions2006Iss. 23, pp. 2907–2907
Citations Over TimeTop 10% of 2006 papers
Abstract
Luminescent lanthanide complexes have been prepared by exploiting the interaction between lanthanide DO3A complexes and chromophore bearing carboxylates or phosphonates. This interaction can be utilised to probe the choice of sensitising chromophore suited to a given lanthanide. Furthermore, ternary complexes obtained from chromophore appended carboxylates dissociate in the presence of phosphate, while those obtained from phosphonates do not.
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