Molecular recognition of oxoanions based on guanidinium receptors
Chemical Society Reviews2006Vol. 36(2), pp. 198–210
Citations Over TimeTop 10% of 2006 papers
Abstract
Guanidinium is a versatile functional group with unique properties. In biological systems, hydrogen-bonding and electrostatic interactions involving the arginine side chains of proteins are critical to stabilise complexes between proteins and nucleic acids, carbohydrates or other proteins. Leading examples of artificial receptors for carboxylates, phosphates and other oxoanions, such as sulfate or nitrate are highlighted in this tutorial review, addressed to readers interested in biology, chemistry and supramolecular chemistry.
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