Silver-catalyzed [2,3]-rearrangement of halonium ylides derived from allyl and propargyl halides and alkyl diazoacetates
Chemical Communications2007Iss. 7, pp. 731–731
Citations Over TimeTop 11% of 2007 papers
Pasupathy Krishnamoorthy, R. Greg Browning, Shreeyukta Singh, Sivappa Rasapalli, Carl J. Lovely, H. V. Rasika Dias
Abstract
A silver(I) complex derived from a polyfluorinated tris(pyrazolyl)borate effectively catalyzes carbene transfer to allylic and propargylic halides, leading to the formation of alpha-haloacetate derivatives.
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