Reaction of imines with N-iodosuccinimide (NIS): unexpected formation of stable 1 : 1 complexes
Chemical Communications2007Iss. 12, pp. 1281–1283
Citations Over TimeTop 10% of 2007 papers
Isabel Castellote, M. C. Morón, Carolina Burgos, Julio Álvarez‐Buílla, Avelino Martı́n, Pilar Gómez‐Sal, Juan J. Vaquero
Abstract
Imines react with N-iodosuccinimide (NIS) to afford unexpected 1 : 1 complexes and the structure of one of these was determined by single-crystal X-ray diffraction; the reaction seems to be very general for substituted cyclic imines with solid stable complexes obtained in high yields; this is the first reported example of a halogen bonding interaction involving the C=N bond and NIS.
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