Two-dimensional hopping motion of encapsulated La atoms in silylated La2@C80
Chemical Communications2007Iss. 26, pp. 2680–2680
Citations Over TimeTop 10% of 2007 papers
Takatsugu Wakahara, Michio Yamada, Satomi Takahashi, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Masahiro Kako, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Shigeru Nagase
Abstract
The 139La NMR study of the exohedrally functionalized derivatives of La2@C80 metallofullerene, La2@C80(Ar2Si)2CH2 (3a: Ar = Mes, Mes = mesityl, 3b: Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C80 cage.
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