Modelling the optical response of gold nanoparticles
Chemical Society Reviews2008Vol. 37(9), pp. 1792–1792
Citations Over TimeTop 1% of 2008 papers
Viktor Myroshnychenko, Jessica Rodríguez‐Fernández, Isabel Pastoriza‐Santos, Alison M. Funston, Carolina Novo, Paul Mulvaney, Luis M. Liz‐Marzán, F. Javier Garcı́a de Abajo
Abstract
This tutorial review presents an overview of theoretical methods for predicting and understanding the optical response of gold nanoparticles. A critical comparison is provided, assisting the reader in making a rational choice for each particular problem, while analytical models provide insights into the effects of retardation in large particles and non-locality in small particles. Far- and near-field spectra are discussed, and the relevance of the latter in surface-enhanced Raman spectroscopy and electron energy-loss spectroscopy is emphasized.
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