Direct observation of change in the molecular structure of benzyl (Z,Z)-muconate during photoisomerization in the solid state
Chemical Communications2007Iss. 1, pp. 55–57
Citations Over TimeTop 16% of 2007 papers
Abstract
For the solid-state photoisomerization of benzyl (Z,Z)-muconate to the corresponding (E,E)-muconate, the direct observation of a change in the crystal structure has revealed that the isomerization occurs by a topochemical reaction process according to a bicycle-pedal model and is finally accompanied by a phase transition to a stable crystal structure.
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