X-Shaped polyphilics: liquid crystal honeycombs with single-molecule walls
Chemical Communications2008Iss. 33, pp. 3861–3861
Citations Over TimeTop 10% of 2008 papers
Robert Kieffer, Marko Prehm, Benjamin Glettner, Karsten Pelz, Ute Baumeister, Feng Liu, Xiangbing Zeng, Goran Ungar, Carsten Tschierske
Abstract
X-Shaped ternary five-block molecules, composed of a rigid p-terphenyl core, two terminal glycerol groups and two flexible n-alkyl or semiperfluorinated chains fixed laterally to opposite sides of the terphenyl moiety, form liquid crystalline phases built up of honeycomb-like arrays of polygonal cylinders, where the rod-like aromatic cores form cylinder walls with a thickness equal to the width of a single molecule.
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