Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation
Chemical Communications2008Iss. 48, pp. 6597–6597
Citations Over TimeTop 10% of 2008 papers
Vincent Pons, R. Tom Baker, Nathaniel K. Szymczak, David J. Heldebrant, John C. Linehan, Myrna H. Matus, Daniel J. Grant, David A. Dixon
Abstract
In situ(11)B NMR monitoring, computational modeling, and external trapping studies show that selectivity and extent of H(2) release in metal-catalysed dehydrogenation of ammonia borane, NH(3)BH(3), are determined by coordination of reactive aminoborane, NH(2)BH(2), to the metal center.
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