Deprotonative cadmation of functionalized aromatics
Chemical Communications2008Iss. 42, pp. 5375–5375
Citations Over TimeTop 10% of 2008 papers
Jean-Martial L’Helgoual’ch, Ghenia Bentabed‐Ababsa, Floris Chevallier, Mitsuhiro Yonehara, Masanobu Uchiyama, A. Derdour, Florence Mongin
Abstract
This communication describes the deproto-metalation of a large range of aromatics including heterocycles using a newly developed lithium-cadmium base; the reaction proceeds at room temperature with an excellent chemoselectivity and efficiency, and proved to be regioselective in most cases.
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