A [Mn18Dy] SMM resulting from the targeted replacement of the central MnIIin the S = 83/2 [Mn19]-aggregate with DyIII
Chemical Communications2008Iss. 5, pp. 544–546
Citations Over TimeTop 10% of 2008 papers
A.M. Ako, Valeriu Mereacre, Rodolphe Clérac, Wolfgang Wernsdorfer, I.J. Hewitt, Christopher E. Anson, Annie K. Powell
Abstract
Anisotropy can be introduced into the [Mn(19)]-aggregate, which currently has the highest known spin ground state of S = 83/2, by the targeted replacement of the central Mn(II) cation with Dy(III) leading to a [Mn(18)Dy] complex with the same core topology showing slow relaxation of the magnetisation.
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