On the remarkable structural diversity and kinetic lability of TpC*CaX complexes (X = NSi2Me6, OC6H4-p-Me, TpC*) where TpC* = tris[3-(2-methoxy-1,1-dimethylethyl)pyrazolyl]hydroborate
Chemical Communications2009Iss. 14, pp. 1828–1828
Citations Over TimeTop 25% of 2009 papers
Abstract
The preparation, structures and solution NMR properties of the title compounds are reported and, remarkably, the compounds (Tp(C)*)(2)M, where M = Ca and Mg, exist as salts in the solid state and undergo facile Tp(C)* ligand exchange in solution.
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