Well-defined donor–acceptor rod–coil diblock copolymers based on P3HT containing C60: the morphology and role as a surfactant in bulk-heterojunction solar cells
Citations Over TimeTop 1% of 2009 papers
Abstract
The synthesis of well-defined rod–coil block copolymers consisting of P3HT donor and C60 acceptor chromophores (P3HT-b-P(SxAy)-C60) in a molecular architecture is reported for use in bulk-heterojunction (BHJ) solar cells. In thin films of the resulting block copolymer, reproducible self-assembly into well-defined “nanofibrils” is observed. This is the first example of a block copolymer containing a C60 derivative that shows exclusively a nanofibrilar structure. We have investigated the potential utility of the block copolymer as a “surfactant” for controlling the interface morphology of the P3HT:PCBM donor–acceptor phase domains within the composite. We find a substantial improvement in device performance when 5% of block copolymer are introduced to the P3HT:PCBM blend system, resulting in ca. 35% improved efficiency relative to the P3HT:PCBM solar cell fabricated without the “surfactant”.
Related Papers
- → Synthesis of Chromophores with Extremely High Electro-optic Activity. 1. Thiophene-Bridge-Based Chromophores(2002)116 cited
- → Using phenoxazine and phenothiazine as electron donors for second-order nonlinear optical chromophore: Enhanced electro-optic activity(2014)55 cited
- → Novel charged NLO chromophores based on quinolizinium acceptor units(2013)29 cited
- → Tuning solid-state fluorescence of a novel group D-π-A chromophores with a reactive hydroxytricyanopyrrole (HTCP) acceptor(2019)17 cited
- → Single Oligomer Spectra Probe Chromophore Nanoenvironments of Tetrameric Fluorescent Proteins(2006)20 cited