An intensely and oxygen independent phosphorescent gold(i)–silver(i) complex: “trapping” an Au8Ag10 oligomer by two gold-alkynyl-diphosphine molecules
Chemical Communications2009Iss. 20, pp. 2860–2860
Citations Over TimeTop 10% of 2009 papers
Igor O. Koshevoy, Yi‐Chih Lin, Antti J. Karttunen, Matti Haukka, Pi‐Tai Chou, Sergey P. Tunik, Tapani A. Pakkanen
Abstract
The molecular heterometallic [{Au(8)Ag(10)(C(2)Ph)(16)}{(PhC(2)Au)(2)PPh(2)(C(6)H(4))(3)PPh(2)}(2)](2+) aggregate of unprecedented topology was obtained and structurally characterized; this compound demonstrates unusually effective phosphorescence, which displays negligible oxygen quenching due to shielding of emissive central cluster by the outer shell of the molecule.
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