Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic–antiaromatic interconversion
Chemical Communications2009Iss. 25, pp. 3762–3762
Citations Over TimeTop 15% of 2009 papers
Harapriya Rath, Naoki Aratani, Jong Min Lim, Jae Seok Lee, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka
Abstract
Metalation of [28]hexaphyrin(1.1.1.1.1.1) with [RhCl(CO)(2)](2) resulted in the formation of an antiaromatic bis-Rh(i) complex, which can be oxidized to an aromatic bis-Rh(i) complex with retention of its rectangular structure.
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