Dipyrrin based luminescent cyclometallated palladium and platinum complexes
Dalton Transactions2009Vol. 39(1), pp. 180–184
Citations Over TimeTop 10% of 2009 papers
Catherine Bronner, Stéphane A. Baudron, Mir Wais Hosseini, Cristian A. Strassert, Aurélie Guénet, Luisa De Cola
Abstract
A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.
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