New catalytic properties of iron complexes: dehydration of amides to nitriles
Chemical Communications2009Iss. 32, pp. 4883–4883
Citations Over TimeTop 10% of 2009 papers
Abstract
Various iron carbonyl clusters such as Fe2(CO)9 or [Et3NH][HFe3(CO)11] are shown to catalyze the dehydration of amides into the corresponding nitriles in the presence of silanes in high yields; this novel protocol showed good functional group tolerance and wide substrate scope.
Related Papers
- → Functionalized fluoroalkyl and alkenyl silanes: Preparations, reactions, and synthetic applications(2008)54 cited
- → Cyclopropyl- and Cyclobutylboronates and -silanes: A Stereoselective Approach(2017)21 cited
- → Stereoselective synthesis of monofluoroalkenyl silanes via copper-catalyzed decarboxylative silylation of α-fluoroacrylic acids(2023)4 cited
- → Silane Coupling Agents(2010)17 cited
- → Les bis-silanes bis-propargyliques comme précurseurs de bis(vinylidène) oxanes et oxépanes(1997)9 cited