A self-repairing, supramolecular polymer system: healability as a consequence of donor–acceptor π–π stacking interactions
Chemical Communications2009Iss. 44, pp. 6717–6717
Citations Over TimeTop 1% of 2009 papers
Stefano Burattini, Howard M. Colquhoun, Justin D. Fox, Donia Friedmann, Barnaby W. Greenland, P. Harris, Wayne Hayes, Michael E. Mackay, Stuart J. Rowan
Abstract
A novel supramolecular polymer system, in which the terminal pyrenyl groups of a polyamide intercalate into the chain-folds of a polyimide via electronically-complementary pi-pi stacking, shows both enhanced mechanical properties relative to those of its individual components and facile healing characteristics as a result of the thermoreversibility of non-covalent interactions.
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