Alkynylcopper(i) polymers and their use in a mechanistic study of alkyne–azide click reactions
Chemical Communications2010Vol. 46(13), pp. 2274–2274
Citations Over TimeTop 10% of 2010 papers
Abstract
Polymeric dinuclear alkynylcopper(I) complexes, for example phenylethynylcopper(I), can be prepared by a robust method involving the interaction of terminal alkynes with copper(II) salts in acetonitrile. The use of the ladder polymers provides heterogeneous catalysts for copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions and provides important mechanistic information.
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