Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp2TiCl
Dalton Transactions2010Vol. 39(37), pp. 8796–8796
Citations Over TimeTop 11% of 2010 papers
Miguel Paradas, Araceli G. Campaña, M.L. Marcos, José Justicia, Ali Haı̈dour, Rafael Robles, Diego J. Cárdenas, J. Enrique Oltra, Juan M. Cuerva
Abstract
The H-atom transfer (HAT) from water to ketyl radicals, mediated by titanocene(iii) aqua-complexes, can explain the Ti(III)-promoted reduction of ketones in aqueous medium better than the conventional House mechanism. Moreover, we also report novel evidences supporting the existence of these titanocene(iii) aqua-complexes.
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